MODEL Compound steam twin cylinder engines are much like the performance of a single, but maybe 10% extra, when the steam is super-heated and the engine gets hot to full working temperature. But MODELS are built:
1 for the pleasure of the build,
2 for the pleasure of just running something you have built,
3 for the pleasure of the specific mechanism,
4 for the pleasure of using the power to drive something :- e.g. A boat, a train, a tractor or traction engine, a generator, a water pump, etc.
Moat people recommend you make a single cylinder engine first, then make a twin next. The Stuart kit you ask about (I think) is their single engine with longer crankshaft to make it a twin.
To answer your question about reciprocating vs. compound, the singles, twins and compounds are all reciprocating engines, but the single has 1 cylinder, the twin has 2 cylinders (nearly twice the power, but twice as complicated) and the compound is a twin, as complicated as the twin to make, but uses only the same amount of steam as the single.... so is more efficient.
Enjoy,
K2