The main boiler tube will try to suck up any heat applied to what you are trying to solder onto it.
I have made boilers to that size, but I used at that time, two MAP type torches, one to play onto the main tube so that it doesn't suck too much heat away and one to get up to temperature around the bits you are trying to solder onto it. It helps having three hands unless you use pallions and a good flux (Tenacity 4A or 5) spread around the joint you are trying to make
I still use the MAP type torches, but only for small stuff, nowadays I have a couple of larger torches running off tanked gas to do large jobs.
John