Assuming it's a cover rather than the pressure vessel itself, I'll recap what I did on mine:
1) Turn the outer profile normally. If the top is rounded you may need a ball turner or else cut in steps and file smooth. Same for the flared bottom profile.
2) The underside is a cylindrical cut to match the radius of the boiler. This can be milled with a fly cutter or by use of a rotary table.
Does this make sense to you?