Brian,
Jumping in with both feet with any machinery can be a very dangerous and expensive exercise, and the milling machine is no exception.
I would suggest you just dip your toes in first, and spend as much time as possible before the machine arrives, on reading up and inwardly digesting the various safety precautions about using a mill.
You will not be able to get anyone here to give you all the information required to operate a mill with reasonable safety and accuracy, because to do it correctly can take many years.
I would suggest as a minimum starting point look for articles on
Climb milling - a very dangerous exercise if you don't know what you are doing. This is the cause of more milling accidents than anything else, and a certainty to be done by a beginner who has never milled before.
Milling cutter types - you need to know the basics of the operation of three basic cutters that are in general use by beginners, slot drill, end mill and fly cutter. All have their own specific uses, and all can be used to do the same sorts of jobs, within the limitations of the cutter.
Setting up and workholding in a vice - it is no use just holding the piece part in the vice and hoping for the best. The vice has to be set up correctly in relationship to the table and cutter, and the job has to be held correctly and safely in the vice jaws in the right position.
If you can read about and understand the three items above, you stand a chance of staying almost safe, if you can just remember to take very small cuts on your initial experiments. Always play safe.
There is a another set of rules, but I would expect you to be using them already, the usual things, safety glasses, no loose clothing etc. You can replace cutters and lumps of metal, but not body parts (well you can, but not very efficiently).
I am sorry about going on about this matter, and not being able to supply the relevent information, but you will soon be starting on another journey, and need to get the correct ticket to get to your destination.
Best of luck on your trip
John