First, my disclaimer: I'm an old retired Electronics Engineer. The only formal education I have on the subject of thermodynamics is that when electronic components get too hot they emit smoke and stop working
So don't take any of my following comments as being factual,...they're just my assumptions based on my observations.
Let me explain how a few of the experiences I've had guide my understanding of how heat is transferred from combustion gasses, through an aluminum tube, and into a liquid flowing inside the tube. I still recall an experiment my high school physics class did which demonstrated several thermodynamic properties. Students constructed a small squarish shaped cup from a single sheet of notebook paper, filled the cup with water, placed the cup above a Bunsen burner, and proceeded to boil the water in the paper cup without burning the very thin notebook paper. The flame from a Bunsen burner is typically around 1,500°C, well above the temperature needed to ignite the paper, and yet the paper remained un-damaged. The water keeps the entire surface and thickness of the paper below the ignition temperature of the paper.
A second example: a propane torch will very quickly melt the walls of an empty aluminum soda can, but fill the soda can with water and you wont be able to melt the aluminum until nearly all the water is gone. This demonstrates that the thin walls of the aluminum can rapidly distribute the 1500°C temperature from the torch into the lower temperature water, and prevents the aluminum from melting. So even though the torch is bathing the outer surface of the Aluminum can in 1500°C gasses, the aluminum wall of the can remains at a much lower temperature.
I believe we can infer that as long as boiler tubes are filled with a rapidly flowing liquid or gaseous working fluid, that the aluminum tubes will remain at, or very close to, the temperature of the working fluid inside the tube, which will not only prevent the aluminum tubes from melting but also prevent the working fluid from reaching decomposition temperatures.
Your thoughts?