S,
You are trying to build one of the hardest engines there is to get running, and I think having to ask what to use, you might be letting yourself in for a lot of heartache.
They look simple enough, but the wrong materials for piston, cylinder and sometimes even the slide valve can contribute to an engine never running.
I have seen people build from respected plans and still not been able to get them to run, even with the correct materials stated on the plans.
Because of the very low powered ones producing so little power, friction can be just one of the reasons an engine will not run. You can get away with odd material mixes on other types of engines, but not on a smallish flamelicker, mainly because of the lower tolerances of the piston/bore clearance to produce that vacuum, where expansion rates come into the formula.
If you can't get cast iron for both (best recommended material) then you will have to do a fair amount of experimentation to get a runner, even then you might never succeed.
I have plans for larger flamelickers, and they use steel tube for the cylinders and cast iron for pistons, but only because they produce more power than their smaller counterparts and can cope with the extra friction produced because of dissimilar metals for those two items.
Big lickers here, where the flywheels are sized at 10" and above, so you can see how large they are.
http://www.gerd-litty.de/vakuummotoren.htm
I am not trying to piddle on your parade, but having been through the learning curve, and come out of the other side as a winner, my twin cylinder even prompted Jan Ridders to have a go at making his own after I had shown him mine, this was when everyone thought a twin cylinder could never be got to work. Then everyone else started to persevere and got theirs going.
If I was you, I would get the plans for say the 'Poppin' (not one of Jan Ridders to begin with, very temperamental) and make it, just to see if you can get your tolerances and materials to work. Then when you have a LOT more understanding of the processes involved, go for it.
[ame]https://www.youtube.com/watch?v=IyrWRBoC-2c[/ame]
John