I've managed to use every collet related thing I've ever bought whether it be 5C or ER. As a result, I do not hesitate to buy more collet related things.
For layout when manual machining, I love my height gage and surface plate. Handiest measuring tools in the shop. For CNC, not so much.
The little Harbor Freight butterfly impact wrench is uber handy. I used one to make a powered drawbar for my mill, and I use another for power tapping. Eventually I'll build a parallelogram arm for it.
Get a box of sharpies and a box of steno pads. Leave them all over the shop. Very handy "tools".
CAD software. Wouldn't want to be without it for all sorts of reasons.
The list goes on and on, those are just a few...