Captain Jerry said:What do you call a shape that has six sides, opposite sides parallel and equal distance apart; six corners with equal angles of 120 degrees. and yet no two edges equal in length?
I believe its a Hexafrustragon.
Your problem starts with having no point of reference to the centre - so start with it turned round or bore a hole (if there's going to be one anyway).
Obviously the RT is the way to go (but you still need your centre reference or its all going to go pear shaped).
On the RT you can otherwise "work your way in" to size after guessing the part to be approximately on center (the hex being your first desired outcome) by this method the center is an outcome rather than a starting point - you will also need to move the clamps at least once.
Clamped to the table (no RT ?) you can clock against a 30° wedge for each "index" - but you still need your centre reference.
After each "index" you have to refind the centre using an edge finder (whatever)
If you can't turn or bore a centre reference - superglue a button - use as reference and remove later. For non-RT use you could also glue a large hex nut to the plate and use that as both angular and radial dimension reference (of course your result will only be as good as the nut).
Ken