Peter, brilliant work, and thank you for sharing it.
Your experiences seem to be spot-on and you have solved many problems. Years ago I worked in a facility that plated conductive slip-rings onto plastic mandrels using the conductive paint method like you. Copper was always used as the base coat because it had excellent "throwing power" and would successfully plate over irregular surfaces. The electrical hot spots of sharp corners and un-plated holes were dealt with by designing them out of the part as best as could be done. Sometimes troublesome parts were removed from the bath and the sharp copper points carefully files off, and then put back into the bath. But it was risky because the plating process did not like to be interrupted.
Once the copper was plated to the mandrel or part, it provided a perfect plating base for a thin plate of nickel or silver or gold. Often, a thin flash plate of copper was used between the different final layers. The original copper plate was smoothed before the final plating was applied. You can always see the thin copper plate underneath the top chrome plate of many kitchen tools, etc, as the chrome wears away.
I am wondering how malleable the copper parts are, and if they respond well to the normal copper annealing process to take care of any work-hardening as the parts are finessed into a perfect fit?
Again, brilliant!