I don't think Owen is searching for the really high silicone content alu but a very popular type is called RSA444 and it is made in Holland by a company called RSP, they are easy to deal with.
Their 30% Si material RSA444 is superb material to work with, I use PCD tips and a good starting point for tips is this company.
PCD Inserts Associated Production Tools (shop-apt.co.uk)
Until you have tried these tips you will not believe how good they are, to be honest they take a small hobby lathe to a whole new level in terms of what can be achieved, the tips are so good they effectively take out machine 'spring back' in tiny cuts which are required when fitting pistons to bores, particularly tapered bores.
I wind the cut on by having the topslide angled at 1 degree and use that to get tiny cuts, it is possible to get a couple of micron cuts this way. On tapered bores where you desire the piston to stop/jam at a certain point in the cylinder then these tiny cuts are used to increment the piston up the bore and it feels very repeatable but the process does rely on the tool actually cutting !!
I more recently have used Garant PCD inserts (265837) these are twice the price of the APT inserts but are tougher.
Be warned these PCD tips are addictive, you will start using them on more and more jobs if you are not careful.
In the photo's you can see the turning operations in an EMCO Compact 5 lathe, an MT2 blank end arbour from Arc Euro trade is machined to pick up on the piston skirt and there is a drawbar that looks like a dummy con rod to pull the piston onto the arbour/mandrel.
The underside of the piston is machined on a Mazak 530 so one extreme to another 'V' the EMCO. To be honest and with care the piston underside could be machined with a manual mill but it just would not have the dainty detail that these have.
Jason is right the high performance glowplug engines can be very consumptive of parts, maybe more like 45 minutes running for a piston across say 30 runs and connecting rod's lifed at 40 runs (they are good for around 80 to 100 runs but failure is catastrophic).
The final picture of the piston sitting upside down is pre OD machining, that finish is roughed down on the Mazak mill to about 0.3mm oversize.
B.