Mechanicboy
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Simple answer is heat, heat is lost to the cylinder walls, piston, head and the fuel. The smaller the cylinder the less heat energy you will get from the air charge. Physics don’t scale very well, especially when it comes to thermal dynamics.
In a model diesel engine with carburator from 0,1 ccm who are smallest and larger is simplere to atomize the fuel in smaller fuel drops and mix into the air before entering in the cylinder and the fuel mix is allready gaseous heated by engine before compression is started to heat up the air. Also the small injector is more difficult to atomize so finer and smaller drops to heat up so quickly to form as gaseous fuel in the small engine who has large heat of loss in surfaces.