Hi Richards (1 and all), I am enjoying your idle speculation. I would suggest however, that a fine improvement on the "conventional" twin (or other) compound would be to really minimise the volume of passage from exhaust valve of HP to intake of LP cylinder. To my mind (vague understanding and idle notions, that is...) most of the wasted heat is from steam expanding between cylinders, so the exhaust pressure of the higher is reduced before becoming the intake of the lower pressure cylinder. - You 30 psi HP exhaust is quite likely to become a 15 psi LP cylinder intake pressure after expanding down a "conventional" U-tube connection pipe, or other. e.g. if you have 30psig in 10% of the HP cylinder when the exhaust valve opens, it is quite conceivable that there is at least the same volume for the steam to expand into just transiting down the connection to get to the intake of the LP cylinder. So the 30psig is down to 15psig when the LP cylinder intake opens. Expanding into a "similar" volume of the LP cylinder (just before the LP piston expands the volume further) the 15psig drops further to say 8psig... which steam is expanded 10 times to 0.8psig.... when the LP exhaust valve opens. That means that the expanding LP cylinder has extracted 90% of 1/3rd of the energy that was expelled from the HP cylinder. I.E. 30% of the exhaust energy from an otherwise "single cylinder" engine. Sounds quite efficient - even more so if you re-write this in Absolute pressure and open the LP exhaust into a condenser, at just a few psi ABS. However, considering the total energy loss (simply!!): The 100psi steam input to the HP cylinder - with 50% cut-off - and assuming 10% volume at exhaust opening - will be below 55psi when the exhaust valve opens. this 55psi steam fills the exhaust valve space, transit pipe and inlet valve space of the LP cylinder so may be down to below 25psi when the LP inlet valve opens. Assuming 10% of LP cylinder volume - which you suggested should be 3 x the HP cylinder volume - then the steam pressure would be below 10psi in the LP cylinder when it is allowed to expand. (To around 1psi?). So we have 100psi x 0.5 HP cylinder volume, expanding 45psi, plus the 9psi expansion in the LP cylinder, makes 54psi (54% of the steam energy putting it crudely!) - less lost heat into the metal and then atmosphere....
It seems to me logical that compounds were successful for power generating stations pumping stations and ships.... but not locomotives (even some compounds were re-timed and fed as simple multi-cylinder engines for the extra power!). You more than double the mass of pistons and cylinders, etc. to gain an extra 10% fuel efficiency... (Probably much less with other heat losses, etc.).
An interesting topic!
K2