Many Copper-Zink alloys carry the imminent danger of so called "stress corrosion cracking".
This phenomenum means a fast cracking of the material caused by the combination of
- mechanical stress
- under the influence of a specific media that will induce the cracking process
There are materials that aren't very sensitive for stress corrosion cracking, but there are materials too, that are very sensitive for this kind of failuring.
- many aluminium alloys
- most 'brass' alloys
- certain steels, f.ex. the very common 1.4301 ('V2A', X5CrNi18-10) steel
- ...
The different materials have certain media that are responsible for stress corrosion cracking. Brass alloys for example are often sensitive to ammonia substances.
The phenomenum of the mentioned stress corrosion cracking is widely investigated by sanitary industry - there are often parts made of brass alloys, that crack because of certain ingedients in the water flowing through them, under influence of inherent stresses (set in the production process or within their assembly).
All materials have, besides their specific attacking media, a certain highth of mechanical stress, that is necessary to start stress corrosion cracking. Brass alloys need internal stresses of only sth. around 10 N/mm² to start the cracking process!
The cracking can proceed relatively slow - within many hours. It can also proceed very very fast - within some seconds to minutes!
And thats the serious danger of brass-made boilers: You can never know, if there's somewhere in it a cracking in process.
You can never know if and when it starts - but when it starts, the boiler will burst suddenly. As the mechanical stresses are most strong in longitudinal direction, this will in general result in a kind of impressive 'explosion' which sets free a high amount of energy.
So, even if many boilers made of brass-alloys work properly, you should as a matter of principle,
never construct and build one of brass.
There's a well made, easy to read & understand report about most common types and causes of stress corrosion cracking. Sadly, it's written in german language. Nevertheless, maybe some can read it. There should be enough Articles like that in english language, as it is a common problem everywhere on the world.
http://www.haustec.cc/docs/spannungsrisskorrosion_allertshammer.pdf
Best regards,
Christian